The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Preface.
Notice to Contributors.
Chapter One Metal Nitrosyl Complexes.
1 Tetranitrosylchromium and Carbonyltrinitrosylmanganese.
2 Dithiocarbamate Complexes of Iron and Cobalt Nitrosyls.
3 Ammine Complexes of Osmium, Including Amminenitrosyls.
4 Nitrosylammineruthenium Complexes.
5 Dinitrosylcobalt Complexes.
6 Bis(triphenylphosphine)chlorodinitrosylruthenium(1+) Tetrafluoroborate.
7 Dicarbonyl--cyclopentadienylnitrosylmolybdenum and Bis(dihalo-- cyclopentadienylnitrosylmolybdenum) Derivatives.
8 Bis(methyldiphenylphosphine)dichloronitrosylcobalt.
9 Tris(triphenylphosphine)nitrosylcobalt and Tris(triphenylphosphine)nitrosylrhodium.
10 Carbonylchloronitrosylrhenium Compounds.
11 Decacarbonyldi--nitrosyl-trimetal Compounds.
12trans-Bis(triphenylphosphine)chloronitrosyliridium(1+) Tetrafluoroborate.
Chapter Two Metal Carbonyl Compounds.
13 Dodecacarbonyltriruthenium.
14 Dodecacarbonyltriruthenium.
15 Hexadecacarbonylhexarhodium.
16 Di--chloro-bis[tricarbonylchlororuthenium(II)].
17 Dicarbonyl(-cyclopentadienyl)(thiocarbonyl)manganese(I).
18 Transition Metal Carbonyl Derivatives of Magnesium.
19 Tris(pentacarbonylmanganese)thalium(III).
20 (Alkylamino)difluorophosphine- and Halodifluorophosphinetetracarbonyliron Complexes.
21 Tris[bis(2-methoxyethyl)ether]potassium and Tetraphenylarsonium Hexacarbonylmetallates(1) of Niobium and Tantalum.
Chapter Three Werner Type Metal Complexes.
22 (Dinitrogen oxide)pentaammineruthenium(II) Salts.
23 Tetrakis(isothiocyanato)bis(2.2'-bipyridine)niobium(IV).
24 Malonato Complexes of Chromium(III).
25 Selenoureametal Complexes.
26 Nickel Tetrafluorooxovanadate(IV) Heptahydrate.
27 Polymeric Chromium(III)-bis(phosphinates).
28 Resolution of thecis-Bromoamminebis(ethylenediamine)cobalt(III) Ion.
29 Bis(alkylphosphine)trichlorotitanium(III) Complexes.
Chapter Four Other Transition Metal Complexes.
30 Reagents for the Synthesis of-Diene Complexes of Tricarbonyliron and Tricarbonylruthenium.
31 Bis()-cyclopentadienylniobium Complexes.
32 Dichloro(1,3-propanediyl)platinum andtrans-Dicholorobis(pyridine)(1,3-propane-diyl)platinum Derivatives.
33 Olefin()silver(I) Compounds.
34 Trichloromethyltitanium and Tribromomethyltitanium.
35 Ethylenebis(triphenylphosphine)palladium(0) and Related Complexes.
Chapter Five Main-Group and Actinide Compounds.
36 Tetraethylammonium, Tetraphenylarsonium, and Ammonium Cyanates and Cyanides.
37 Diindenylmagnesium.
38 Fluoromethylsilanes.
39 Uranium Hexachloride.
40 Cholorotris(-cyclopentadienyl) Complexes of Uranium(IV) and Thorium(IV).
Chapter Six Ligands Used to Prepare Metal Complexes.
41 Trimethylphosphine.
42 Tertiary Phosphines.
43 Diphenylphosphine.
44 Tri(phenyl-d3)phosphine.
45 Methyl Difluorophosphite.
46 Bi-, Tri-, and Tetradentate Phosphorus-Sulfur Ligands.
47 Tetradentate Tripod Ligands Containing Nitrogen, Sulfur, Phosphorus, and Arsenic as Donor Atoms.
48 Dimethyl(pentafluorophenyl)phosphine and Dimethyl(pentafluorophenyl)arsine Ligands.
49 Tris(-dimethylarsinophenyl)arsine and Tris(-dimethylarsinophenyl)stibine.
50cis-2-Diphenylarsinovinyldiphenylphosphine and 2-Diphenylarsinoethyldiphenylphosphine.
51 [2-(Isopropylphenylphosphino)ethyl]diphenylphosphine.
52 [(Phenylisopropylphosphino)methyl]diphenylphosphine Sulfide.
53N,N,N',N'-Tetrakis(diphenylphosphinomethyl)ethylenediamine.
54 Ethylenebis(nitrilodimethylene)tetrakis(phenylphosphinic acid).
55 [2-(Phenylphosphino)ethyl]diphenylphosphine.
56 1,1,1-Trifluoro-4-mercapto-4-(2-thienyl)-3-buten-2-one.
Chapter Seven Compounds of Biological Interest.
57 Metalloporphyrins.
58 (1,4,8,11-Tetraazacyclotetradecane)nickel(II) Perchlorate and 1,4,8,11-Tetraazacyclotetradecane.
59N,N'-Ethylenebis(monothiacetylacetoniminato)cobalt(II) and Related Metal Complexes.
60 Metallatranes.
61cis-Bis(diethyldithiocarbamato)dinitrosylmolybdenum.
62 Some-Cyclopentadienyl Complexes of Titanium(III).
Index of Contributors.
Subject Index.
Formula Index.
