Understanding of oxorhenium(V) Rhenium(V) complexes as radiopharmaceuticals for therapy and diagnosis have received attention, because of their suitable radionuclear properties, i.e., 186Re: Emax = 1.1 MeV for beta-emission and Emax = 0.137 MeV for gamma-emission with t1/2 = 90.6 h, 188Re: Emax = 2.1 MeV for beta-emission and Emax = 0.155 MeV for gamma-emission with t1/2 = 17 h. Hence, chemical properties of various monooxo- and dioxorhenium(V) (ReO3+ and ReO2+) complexes have been examined as basic studies for their application to radiopharmaceutical. However, only limited information is available concerning the electrochemical properties and stereoisomerism of oxorhenium(V) complexes in non-aqueous solutions, in spite of importance in the relation to in vivo behavior, i.e., the reactivity towards redox agents. This book is covering a doctoral study and its results on the related subjects.

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Ali Canlier obtained his PhD in nuclear engineering at Tokyo Institute of Technology, Tokyo. He is currently a Research Fellow in the Graduate School of EEWS at KAIST, where he is carrying out a research on Boron chemistry and meso-/nanomaterials. He can speak Turkish, English and Japanese fluently, Korean and German as a beginner.